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dc.contributor.advisorSmith, Thomas J. (Thomas Joseph), 1949-
dc.contributor.advisorVerani, Claudio N.
dc.contributor.authorGross, Bethany C.
dc.date.accessioned2012-01-09T15:57:45Z
dc.date.available2012-01-09T15:57:45Z
dc.date.issued2009
dc.identifier.urihttp://hdl.handle.net/10920/24482
dc.descriptionviii, 46 p.en_US
dc.description.abstractModem semiconductor devices now have feature dimensions less than 0.1 Jl.m, but the capacitor in DRAM circuits of computers is not yet able to scale down to the necessary dimensions. Creating a smaller, more efficient capacitor (one able to store more information) is the next step in enhancing semiconductors. To achieve a more efficient capacitor on such a small scale, a compound needs to be synthesized that is highly redox active and able to form SAMs on a gold surface for use in computer DRAMs. The precursor ligands MeMPTP and MPTP were synthesized and characterized in order to synthesize a copper-ligand coordinated species, [Cu11MeMPTP]Ch, and the capped ligand [Cu11LtHBPA]. The redox activity of [Cu11MeMPTP]Ch and [Cu11LtHBPA] was established using cylclic voltometry and resulted in. a reversible redox process for Cu1 to Cu11 in both compounds, and nonreversible processes for their respective ligands. Knowing that these compounds possess the potential for redox activity, namely with copper at the metal center, allows for. future improvement of the compound on the basis of increased redox capability.en_US
dc.description.sponsorshipDepartment of Chemistry. Wayne State University. Detroit, Michigan.
dc.format.mimetypeapplication/pdf
dc.language.isoen_USen_US
dc.publisherKalamazoo Collegeen_US
dc.relation.ispartofKalamazoo College Chemistry Senior Individualized Projects Collection
dc.relation.ispartofseriesSenior Individualized Projects. Chemistry.;
dc.rightsU.S. copyright laws protect this material. Commercial use or distribution of this material is not permitted without prior written permission of the copyright holder. All rights reserved.
dc.titleSynthesis and Characterization of Metal Complexes with Terpy-derivatives for SAM filmsen_US
dc.typeThesisen_US
KCollege.Access.ContactIf you are not a current Kalamazoo College student, faculty, or staff member, email dspace@kzoo.edu to request access to this thesis.


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  • Chemistry Senior Individualized Projects [820]
    This collection includes Senior Individualized Projects (SIP's) completed in the Chemistry Department. Abstracts are generally available to the public, but PDF files are available only to current Kalamazoo College students, faculty, and staff.

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