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Investigation of the Rearrangement of Organic Macrocycle N,N'–dimethyltribenzo–1,4,7–triazacyclononane to 5,9–dimethyl–5,9-dihydroquinoxalino–[3,2,1–de]phenazine Cation Radical by Copper(II) Oxidation
(Kalamazoo College, 2015)
The goal of this project was to extend the results from previous studies, as well as produce and characterize the 5,9–dimethyl–5,9-dihydroquinoxalino–[3,2,1–de]phenazine cation radical formed by Ross Beattie (2010), as it ...
A New Type of Nitrogen Cation Radical Generated from Copper(II)-Induced Oxidation of the Nine-Membered Macrocycle N,N'–Dimethyltribenzo–1,4,7–triazacyclononatriene
(Kalamazoo, Mich. : Kalamazoo College, 2016)
Nitrogen-containing, small-ring macrocycles display varied reactivity toward transition metals. In this project copper(II) bromide was used originally in an attempt to form stable Cu(II) complexes. Copper(II) bromide has ...