Intramolecular Alkylation During the Reaction of Aryldiazonium Salts

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Authors
Makowski, David N.
Issue Date
1975
Type
Thesis
Language
en_US
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Abstract
The purpose of this SIP was to study the influence of reaction conditions upon the intramolecular alkylation of aryldiazonium salts. Intramolecular alkylation occurred most readily in a cold, acidic medium. It also occurred in an aprotic medium, but in only modest yield. With the introduction of HCl by means of the hydrochloride 2,5-di-i-butyl-aniline hydrochloride the yield of 2-methyl-5-i-butylbenzene in the aprotic medium doubled.
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47 p.
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Kalamazoo College
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U.S. copyright laws protect this material. Commercial use or distribution of this material is not permitted without prior written permission of the copyright holder. All rights reserved.
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