The Synthesis and Characterization of Multiply Bonded Molybdenum and Rhenium Complexes Containing Monodentate and Bidentate Phosphines
Abstract
The specific focus of this thesis is multiply-bonded
molybdenum and rhenium complexes with monodentate and
bidentate phosphine ligands. Included is a study of
the series, M02Cl4(PR3)4 in attempts to establish a
correlation between the δ-δ* transition energy and
published NMR and IR spectral parameters. Attempts
with rhenium and monodentate phosphines is also
discussed. The work with the bidentate ligand dppp
(1,2 bis(diphenylphosphino) propane) is discussed with
several interesting results. Also the initial work with
dppben (1,2 bis(diphentlphosphino) benzene is
discussed, with reference to the molybdenum analogs. If you are not a current K College student, faculty, or staff member, email dspace@kzoo.edu to request access to this SIP.