The Isomeric Separation, Stereochemistry, and Kinetics of Thermal Isomerization of [3' aα, 4'α,7'α,7'aα]-3'a,4',7',7'a-tetra-hydro-spiro(syn-2-methyl-1,8'-cyclopropane)-4',7'-methanoisobenzofuran-1'3'-dione
Cast, Todd K.
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Since its conformation in 1928 through the work of Diels and Alder, the Diels-Alder reaction has been a topic of great interest to chemists because of its universal application, relative ease of occurrence, and intriguing mechanism of cycloaddition. Both the forward and reverse Diels-Alder reaction can be used to prepare compounds impossible to prepare by other means. It has also found widespread use because of its regiospecific and stereospecific properties. The simplest Diels-Alder reaction is the reaction between ethylene and 1,3-butadiene to yield cyclohexene.If you are not a current K College student, faculty, or staff member, email firstname.lastname@example.org to request access to this SIP.
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A Kinetic Study of the Endo-Exo Isomerization of the Cyclopentadiene-Maleic Anhydride Diels-Alder Adduct and the Attempt to Catalyze the Rearrangement with Lewis Acids Schafer, Wes Allen (Kalamazoo, Mich. : Kalamazoo College., 1985)
Electronic Effects Upon the Barrier to Syn-Anti Isomerization in Substituted Acetone N-Phenylimines McDevitt, William J. (Kalamazoo College, 1975)The kinetics of syn-anti isomerization about the carbon-nitrogen double bond of acetone N-phenylimine and its p-chloro, p-fluoro, p-methyl, and p-methoxy derivitives have been studied. The free energies of activation at ...