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dc.contributor.advisorSmith, Thomas J. (Thomas Joseph), 1949-
dc.contributor.authorBrodsky, Kari
dc.date.accessioned2010-02-10T16:35:32Z
dc.date.available2010-02-10T16:35:32Z
dc.date.issued2006
dc.identifier.urihttp://hdl.handle.net/10920/12616
dc.descriptionvii, 108 p.
dc.description.abstractIn this research project, copper(II) coordination chemistry was investigated through synthesis and analysis copper (II) compounds containing organic ligands mimicking amino acids in metalloproteins. Diphenylacetic, I-Naphthoxyacetic, and 2-Napthoxyacetic were the carboxylic acids applied. The imines used were pyridine, 2,2'-bypridine, and 7-azaindole. Three novel copper coordination compounds, dinuclear C~(lNaphOCH2CO~ 4(NCCH3)2-2CH3CN, C~(Ph2CHCO~4(NC6HJ-2(N03)' and C~(Ph2CHCO~6(bpY)2(BF J-2CH3CN, were produced and characterized. Structural characterizations of these compounds in addition to several other copper (II) compounds were done using X-ray crystallography and infrared, electronic absorption, and Raman spectroscopy. Dinuclear paddle wheel structures were the most common structural arrangements identified. Inventories of the new structures were typified by different nuclearity, coordination, and binding m~des, specifically carboxylate shifts.en_US
dc.format.mimetypeapplication/pdf
dc.publisherKalamazoo Collegeen_US
dc.relation.ispartofKalamazoo College Chemistry Senior Individualized Projects Collection
dc.relation.ispartofseriesSenior Individualized Projects. Chemistry;
dc.rightsU.S. copyright laws protect this material. Commercial use or distribution of this material is not permitted without prior written permission of the copyright holder. All rights reserved.
dc.titleSynthesis and Characterization of Transition Metal Compoundsen_US
dc.typeThesisen_US


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    This collection includes Senior Individualized Projects (SIP's) completed in the Chemistry Department. Abstracts are generally available to the public, but PDF files are available only to current Kalamazoo College students, faculty, and staff.

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